کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
228620 | 464845 | 2011 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
MoO3/SiO2 catalysts for double bond migration of 2-butene
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: MoO3/SiO2 catalysts for double bond migration of 2-butene MoO3/SiO2 catalysts for double bond migration of 2-butene](/preview/png/228620.png)
چکیده انگلیسی
The objective of the present study is to investigate the performance of MoO3/SiO2 as a catalyst for double bond migration from 2-butene to 1-butene. The effects of MoO3 addition on catalytic properties over SiO2 were analyzed through BET surface area, XRD, ammonia-temperature programmed desorption (NH3-TPD) and FT-IR of adsorbed pyridine. The highest activity of the 10% MoO3/SiO2 catalyst in double bond migration of 2-butene can be explained by the highest number of the weak acid sites. Based on the NH3 TPD and the FT-IR of pyridine adsorption results, the increase in the overall number of acid sites can be ascribed to an increase in the number of Lewis sites by the addition of MoO3.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Industrial and Engineering Chemistry - Volume 17, Issue 2, 25 March 2011, Pages 186–190
Journal: Journal of Industrial and Engineering Chemistry - Volume 17, Issue 2, 25 March 2011, Pages 186–190
نویسندگان
Young-Kwon Park, So Jeong Kim, Nansuk You, Jungho Cho, Seong Jun Lee, Jae Ho Lee, Jong-Ki Jeon,