کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
228816 | 464850 | 2014 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Solvent free synthesis of coumarin derivative by the use of AlSBA-1 molecular sieves
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
AlSBA-1 molecular sieves were synthesized successfully and used for the synthesis of coumarins through Pechmann condensation. The synthesized AlSBA-1 catalysts were characterized by XRD, BET, SEM, FTIR, TGA techniques. The synthesized materials possess large surface area with mesopores. Pechmann condensation of 3-methoxyphenol and ethyl acetoacetate was carried out under solvent free condition and 7-methoxy-4-methylcoumarin was the main product. The selectivity of the product was found to be 74.04%. Among the synthesized catalysts, AlSBA-1(2) showed high activity than others due to high density of acid sites. Hence, AlSBA-1 molecular sieves a better choice of catalyst for the synthesis of coumarins.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Industrial and Engineering Chemistry - Volume 20, Issue 3, 25 May 2014, Pages 953–960
Journal: Journal of Industrial and Engineering Chemistry - Volume 20, Issue 3, 25 May 2014, Pages 953–960
نویسندگان
Mei Mei Peng, Pushparaj Hemalatha, Mani Ganesh, Muthiahpillai Palanichamy, Hyun Tae Jang,