کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
229136 | 464859 | 2012 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of 9H-fluoren-9-yl benzodithioates and their application as reversible addition–fragmentation chain transfer agents in living radical polymerization of styrene
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis of 9H-fluoren-9-yl benzodithioates and their application as reversible addition–fragmentation chain transfer agents in living radical polymerization of styrene Synthesis of 9H-fluoren-9-yl benzodithioates and their application as reversible addition–fragmentation chain transfer agents in living radical polymerization of styrene](/preview/png/229136.png)
چکیده انگلیسی
The reversible addition–fragmentation chain transfer (RAFT) polymerization is one of living radical polymerizations. In this study, four different 9H-fluoren-9-yl benzodithiolates (FBDTs) were synthesized, and used along with azobis(isobutyronitrile) (AIBN), a radical initiator, in polymerization of styrene (ST) at the molar ratio of 3:1. This new transfer agent exhibited the typical characteristic living free radical polymerization behaviors such as good control of molecule weight and narrow molecule weight distribution. It was concluded that the FBDTs can be used as the RAFT agents in free radical polymerization of vinyl monomers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Industrial and Engineering Chemistry - Volume 18, Issue 2, 25 March 2012, Pages 865–869
Journal: Journal of Industrial and Engineering Chemistry - Volume 18, Issue 2, 25 March 2012, Pages 865–869
نویسندگان
Yong Liu, Chun-He Lee, Yu-Zi Jin, Jian Huo, Youn-Sik Lee,