کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
236188 465664 2014 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of phosphorus and water contents on physico-chemical properties of SAPO-34 molecular sieve
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Effect of phosphorus and water contents on physico-chemical properties of SAPO-34 molecular sieve
چکیده انگلیسی


• SAPO-34, a molecular sieve for light molecule separation and catalytic application.
• SAPO-34 molecular sieves with different P and H2O contents were synthesized.
• When the P2O5/Al2O3 molar ratio was 1.4, the SAPO-41 co-crystallized with SAPO-34.
• Relatively ill-defined pattern appeared when water content was 100.
• Samples with P2O5/Al2O3 and H2O/Al2O3 of 1 and 60 had the best crystallinity.

SAPO-34 molecular sieves with different P and H2O contents were synthesized by adjusting P2O5/Al2O3 and H2O/Al2O3 molar ratios in starting gel. The crystal structure, crystal size, elemental composition, and acid site density of the synthesized samples were characterized with XRD, SEM, ICP, TPD, and FTIR. The morphology, crystallinity, and acidity of SAPO-34 materials varied with P2O5/Al2O3 and H2O/Al2O3 molar ratios in the starting gel and different Si substitution mechanisms were accompanied correspondingly. Samples with P2O5/Al2O3 and H2O/Al2O3 molar ratios of 1 and 60 had the best crystallinity with the largest crystals and maximum surface area. Increasing the concentration of strong acidic hydroxyl groups for samples SP-1 and SW-60 indicated the presence of a higher amount of Bronsted acid sites.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Powder Technology - Volume 259, June 2014, Pages 81–86
نویسندگان
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