Effect of excess Nb2O5 on the growth behavior of KSr2Nb5O15 particles by molten salt synthesis

The single-step and two-step molten salt synthesis (MSS) methods have been utilized to synthesize anisometric KSr2Nb5O15 (KSN) particles. To facilitate morphological and dimensional control, the effects of excess Nb2O5 on the growth behavior of the product particles have been investigated, and a defect reaction growth mechanism is proposed. It was found that excess Nb2O5 could promote the growth of product particles in both the single-step and two-step MSS. The aspect ratio of the product particles increased and reached the maximum value (16.85 for the single-step MSS and 52.29 for the two-step MSS), then decreased with increasing amounts of excess Nb2O5. Using single-step MSS, two morphologies (rod-like and columnar) were formed as the excess Nb2O5 content was changed. This was caused by the nucleation of new particles at the particle edges. However, needle-like KSN particles were observed in the two-step MSS, which can be explained by the defect reaction mechanism. The in situ epitaxial growth, as controlled by the defect reaction mechanism, determines the morphology and size of the particles obtained using the two-step MSS.

► The KSN particles with aspect ratio higher than 50 can be synthesized.
► The morphology of KSN particles is closely related to the content of Nb2O5.
► KSN crystal growth is controlled by a defect reaction mechanism for the two-step MSS.The crystal growth of KSN particles by the single-step MSS is controlled by the conventional solution-diffusion mechanism, and the morphology varied from rod-like shape to columnar structure. For the two-step MSS, the product particles were the needle-like shape and the defect reaction growth mechanism was proposed.Figure optionsDownload as PowerPoint slide