Magnetic and Mössbauer behavior of the nanostructured MgFe2O4 spinel obtained at low temperature

This study investigated the solution combustion synthesis technique to obtain the nanostructured magnesioferrite (MgFe2O4) spinel powder. The reaction was performed in an electric muffle furnace. Considering the characteristics of the as-synthesized powders, the 30% fuel-deficient formulation was selected for synthesis temperature evaluation. This formulation was synthesized at different furnace temperatures. Powder characterization was carried out by X-ray diffraction (XRD) to evaluate crystallographic analysis and crystallite size; Transmission Electron Microscopy (TEM) was done to assess the morphology and crystallite size; and Mössbauer spectroscopy and vibrational sample magnetometer (VSM) were performed to obtain magnetic measurements. Crystallite sizes estimated from the XRD technique increased with furnace temperature values, which were consistent with the results obtained by TEM. The characterized samples of MgFe2O4 had an average crystallite size of 42.8 nm using the DRX method, average saturation magnetization of 25.6 emu/g and coercive field not higher than 11 Oe.

This study reports the synthesis of MgFe2O4 via SCS in low temperature using iron nitrate, magnesium nitrate and maleic anhydride as fuel. We prepared MgFe2O4 on different molar compositions between fuel and nitrate, and subsequently at different furnace temperatures, to analyze the behavior of particles growth and their magnetic and structural relationship of samples as obtained.Figure optionsDownload as PowerPoint slideResearch highlights
► Synthesis of MgFe2O4 via SCS in low temperature using maleic anhydride as fuel.
► We prepared MgFe2O4 on different molar compositions for fuel and temperatures.
► We analyzed MgFe2O4 from characterizations structural and magnetic.