Computational fluid dynamics and electrostatic modeling of polymerization fluidized-bed reactors

Electrostatics plays an important role in gas–solid polymerization fluidized-bed reactors. Agglomeration of polymer particles can occur due to either electrostatic and/or thermal effects, and can lead to reactor operability problems if not properly mitigated. In this work a first-principles electrostatic model is developed and coupled with a multi-fluid computational fluid dynamic (CFD) model to understand the effect of electrostatics on the bulk polymer, polymer fines, and catalyst particles. The multi-phase CFD model for gas–solid flow is based on the kinetic theory of granular flows and the frictional theory. The electrostatic model is developed based on a fixed, size-dependent charge for each type of particle (catalyst, polymer fines and polymer). The combined CFD model is first verified using simple test cases and then applied to a pilot-plant-scale polymerization fluidized-bed reactor. The multi-phase CFD model is applied to reproduce qualitative trends in particle segregation and entrainment due to electrostatic charges observed in experiments.

Electrostatics is known to influence fluidized-bed dynamics. In this work, an electrostatic model developed from first principles is coupled with multi-fluid computational fluid dynamic model. The model is verified with simple test cases and applied on a pilot-scale plant fluidized-bed reactor. The combined CFD model predicted the hydrodynamic and electrostatic segregation patterns observed in experiments.Figure optionsDownload as PowerPoint slide