A PVB-based rheological phase approach to nano-LiFePO4/C composite cathodes

Nano-LiFePO4/C cathode materials were synthesized by a PVB-based rheological phase method, followed by calcination at 550 °C for 10 h in argon. Simultaneous thermogravimetric-differential scanning calorimetry analysis indicates that the crystallization temperature of LiFePO4 is about 436 °C. In the process of heat treatment, the decomposition of polyvinylbutyral coats carbon on the synthesized LiFePO4 particles in situ. The resulting LiFePO4 powders with fine particle sizes and homogeneous carbon network connection were observed by using scanning electron microscopy and transmission electron microscopy. Electrochemical measurements show that the LiFePO4/C composite cathode delivers a large discharge capacity of 162.3 mAh·g− 1 at the 0.1 C rate, and exhibits a favorable capacity cycling maintenance at lower charge and discharge rate such as 0.5 C rate.

Carbon-coated LiFePO4 powders with an average particle size about 65 nm have been successfully synthesized by a new PVB-based rheological phase method. The favorable physical characteristics of the composite materials as cathode for lithium-ion batteries exhibit good electrochemical performances.Figure optionsDownload as PowerPoint slide