کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4762523 1362212 2017 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Molten-salt synthesis of tetragonal micron-sized barium titanate from a peroxo-hydroxide precursor
ترجمه فارسی عنوان
سنتز متیل نمک تیتانات باریم تتراگونال میکرون از یک پیش ساز هیدروکسید پراکسو
کلمات کلیدی
سنتز نمک نمک، تیتانات باریم، پیشکسیر هیدروکسید پروکسو، مرفولوژی،
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی


- The Ba-Ti-precursor was transformed to BaTiO3 at 1080 °C with Ba/Ti ratio of unity.
- BaTiO3 with different morphologies were formed depending on the heating profile.
- The salt type and concentration influenced the habit-plane growth of BaTiO3.
- Cube-shaped BaTiO3 was formed in NaCl-KCl with either {0 0 1} or {1 0 1} habit-planes.
- Hexagonal-shaped BaTiO3 was synthesized in Na2SO4-K2SO4 with {1 1 1} habit-planes.

Barium titanate (BaTiO3) was produced from an barium-titanate-peroxo-hydroxide precursor material in NaCl-KCl and Na2SO4-K2SO4 salt mixtures or fluxes at temperatures up to 1080 °C via the molten-salt synthesis (MSS) method. Beside the different salt mixtures several other parameters were studied to determine the effect on the particle morphology. A relatively fast heating rate and a relatively high salt to precursor ratio resulted in a highly faceted morphology. The effect of the salt flux was clearly seen in the morphology of BaTiO3 obtained by MSS at 1080 °C. Cube-shaped particles were observed for the chloride-flux-grown BaTiO3 while hexagonal-shaped flat particles were observed for the sulfate-flux-grown BaTiO3. BaTiO3 particles produced in the chloride-flux were either {1 0 1} or {0 0 1} faceted. The hexagonal surface of the sulfate-flux-grown BaTiO3 was {1 1 1} faceted.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Advanced Powder Technology - Volume 28, Issue 1, January 2017, Pages 146-154
نویسندگان
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