کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4766020 1423895 2017 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis, characterisation and photophysical studies of oxadiazolyl coumarin: A new class of blue light emitting fluorescent dyes
ترجمه فارسی عنوان
سنتز، خصوصیات و مطالعات فتوفیزیکال اکسیدیاازولیل کومارین: یک کلاس جدید از رنگهای فلورسنت، تابش آبی رنگ
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی
A library of novel 1, 2, 4-oxadiazole linked coumarin dyes have been synthesised via condensation of corresponding acid 6 and N'-hydroxybenzimidamide 8. This new class of organic compounds were examined for their fluorescent properties and found to emit blue light in the visible region of the spectrum with very high Stoke's shift values. Most of these compounds demonstrated high quantum yields and fluorescence life time in nano-second range which makes them quite lucrative to be used as new fluorescent probes. The highest quantum yield of 0.68 was shown by compound 9j which also shows high Stoke's shift value. The electronic structure of these coumarin-based donor-π-acceptor (D-π-A)-type organic dyes have been examined by Density Functional Theory (DFT). TGA analysis of few of the compounds show that they are stable up to temperature range of 0-245 °C. The synthesised compounds were characterised by NMR and mass spectrometry and the structure of two of these compounds have been confirmed by X-ray crystallography.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 140, May 2017, Pages 250-260
نویسندگان
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