کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4766269 | 1423897 | 2017 | 31 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and characterization of a new high NIR reflective ytterbium molybdenum oxide and related doped pigments
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A novel yellow NIR reflecting pigment with the formula Yb6Mo2O15 crystallizing in a trigonal structure with the color coordinates L* = 88.7, a* = â6.6, b* = 55.0, C* = 55.4, and h° = 96.8 is described. Color variation from pale yellow to brick-red was realized by partial substitution of Yb3+ or Mo6+ with various metal ions. The novel pigments of the formula Yb6âxDxMo2O15±δ (D = Na, Ca, Ti, Bi) and Yb6Mo2âxMxO15âδ (M = Na, Fe, Co, Nb, Bi) were characterized by powder XRD and UV-Vis-NIR diffuse reflectance spectroscopy. The high NIR solar reflectance of Yb6Mo2O15 of 93.7% (PTFE used as reference) was further improved with Yb5.4Ti0.6Mo2O15+δ and Yb6NbMoO15âδ reaching values of 99.4%, and 99.7%, respectively. Finally, the potential of the new rare earth molybdenum oxides for use as cool pigments in rooftop applications was demonstrated by the developed brick-red compound Yb6Mo1.6Fe0.4O15âδ having an enlarged band gap of 2.46 eV in comparison to 2.3 eV for Yb6Mo2O15. Furthermore, Yb6Mo1.6Fe0.4O15âδ exhibits an impressive NIR reflectivity of 90.4%.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 138, March 2017, Pages 90-99
Journal: Dyes and Pigments - Volume 138, March 2017, Pages 90-99
نویسندگان
Daniel Schildhammer, Gerda Fuhrmann, Lucas Petschnig, Nikolaus Weinberger, Herwig Schottenberger, Hubert Huppertz,