کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
4766345 | 1423898 | 2017 | 38 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Conjugated dyes carrying N, N-dialkylamino and ketone groups: One-component visible light Norrish type II photoinitiators
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Conjugated dyes carrying N, N-dialkylamino and ketone groups: One-component visible light Norrish type II photoinitiators Conjugated dyes carrying N, N-dialkylamino and ketone groups: One-component visible light Norrish type II photoinitiators](/preview/png/4766345.png)
چکیده انگلیسی
This work presents new conjugated dyes carrying N, N-dialkylamino and ketone groups for using as one-component Norrish type II visible light photoinitiators. The novel dyes without ketone group were also synthesized to compose two-component visible light photoinitiators for comparisons. The target dyes show the remarkable absorption in visible light region. Photo-differential scanning calorimetry was employed to study visible light photoinitiating polymerization kinetics of methyl methacrylate by new one-component photoinitiators and two-component photoinitiators respectively. The results suggest that the one-component photoinitiators showed much more efficient photoinitiating polymerization of methyl methacrylate than the two-component photoinitiating systems under visible light irradiation. The molecular weight of visible light photopolymer produced by the new photoinitiators was determined. The visible light photoinitiating mechanism of the one-component photoinitiators was studied by absorption and emission spectra, electron spin resonance spectra and cyclic voltammograms analysis.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Dyes and Pigments - Volume 137, February 2017, Pages 456-467
Journal: Dyes and Pigments - Volume 137, February 2017, Pages 456-467
نویسندگان
Ge Ding, Chuan Jing, Xiaozhuan Qin, Yulong Gong, Xueping Zhang, Shengtao Zhang, Ziping Luo, Hongru Li, Fang Gao,