کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4766580 1423978 2017 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A soluble phenolic mediator contributing to enhanced discharge capacity and low charge overpotential for lithium-oxygen batteries
ترجمه فارسی عنوان
یک واسطه فنول محلول در افزایش ظرفیت تخلیه و بارگذاری کم در باتری های باتری لیتیوم اکسیژن
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی


- 2,6-Di-tert-butyl-hydroxytoluene (BHT) is employed as a soluble redox mediator.
- BHT increases discharge capacity and reduces charge overpotential simultaneously.
- In-situ XRD was used to detect the formation and decomposition of Li2O2.

In this study, a phenolic antioxidant of 2,6-di-tert-butyl-hydroxytoluene (BHT) is applied in Li-O2 batteries to simultaneously improve discharge capacity and reduce charge overpotential. BHT exhibits a redox couple at ~ 3.0 V (vs. Li+/Li), which is extremely close to the thermodynamic potential of a Li-O2 battery (2.96 V). The unique chemical and electrochemical behaviors of BHT contribute to the improvement on both oxygen reduction reaction and oxygen evolution reaction performances. These factors lead to the notable enhancement of discharge capacity (capacity increases by 72%) and the reduction of charge plateau (the plateau is 3.2 V and 4.2 V, respectively, with and without BHT) for Li-O2 batteries. Furthermore, in-situ X-ray diffraction results confirm that the BHT-mediated formation and decomposition of Li2O2, rather than parasitic reactions, dominate the discharge and charge processes. The results provide a new approach for exploiting appropriate soluble mediators for rechargeable Li-O2 batteries.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochemistry Communications - Volume 79, June 2017, Pages 68-72
نویسندگان
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