کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4985274 1454505 2017 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of scalable and tunable slightly oxidized graphene via chemical vapor deposition
ترجمه فارسی عنوان
سنتز گرافن قابل مقایسه و قابل تنظیم گرافیتی کمی اکسید شده از طریق رسوب بخار شیمیایی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی شیمی کلوئیدی و سطحی
چکیده انگلیسی

Semiconducting, large sheets of carbon as an active material in optoelectronic research are missing and reduced graphene oxide (rGO) can be a good candidate. However, chemical synthesis cannot produce large sheets of rGO (i.e. maximum: 20–30 μm) as well as high quality rGO due to the restraints of fabrication method. Thus, a novel strategy for the synthesis of large sheets of semiconducting rGO is urgently required. Large area slightly oxidized graphene (SOG) is fabricated at the interface of silicon dioxide (SiO2) and silicon via   Chemical Vapor Deposition (CVD) method, herein for the first time. Carbon atoms bond with oxygen functionalities (i.e. CO, COH) at the time of diffusion in SiO2 allowing for C/O ratios from 7 to 10 adjustable by the variation of SiO2 thickness, indicating the tunable oxidation. Moreover, electronic structure and morphology of SOG are similar to the chemically grown rGO. The fabrication mechanism of SOG is also investigated.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Colloid and Interface Science - Volume 490, 15 March 2017, Pages 844–849