کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
4985442 1454508 2017 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Regular ArticleZ-scheme mechanism of photogenerated carriers for hybrid photocatalyst Ag3PO4/g-C3N4 in degradation of sulfamethoxazole
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
Regular ArticleZ-scheme mechanism of photogenerated carriers for hybrid photocatalyst Ag3PO4/g-C3N4 in degradation of sulfamethoxazole
چکیده انگلیسی

Composite or hybrid photocatalysts are gaining increasing interests due to the unique and enhanced photocatalytic activity. In this study, Ag3PO4/g-C3N4 with different ratios of Ag3PO4 and g-C3N4 were synthesized using a facile in situ precipitation method. The photocatalysts were characterized by transmission electron microscopy (TEM), X-ray diffraction pattern (XRD), Fourier transform infrared spectra (FTIR), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET) and ultraviolet-visible diffuse reflectance spectroscopy (UV-vis DRS). The photocatalytic performance was evaluated by the degradation of sulfamethoxazole (SMX), a model antibiotic compound, under visible light irradiation. It was found that the composite photocatalyst Ag3PO4/g-C3N4 with a mass ratio of Ag3PO4:g-C3N4 of 98:2 exhibited a higher photocatalytic activity than Ag3PO4/g-C3N4 with the mass ratio of 2:98 for the degradation of SMX. When Ag3PO4 was the primary part of Ag3PO4/g-C3N4 photocatalyst, the migration of photogenerated electron-hole showed a Z-scheme mechanism with photongenerated holes on the valance band of Ag3PO4 to oxidize pollutants. The separation mechanism was investigated by the photoluminescence technique and the scavengering of reactive oxygen species.

When Ag3PO4 was the primary part of Ag3PO4/g-C3N4, the migration of photogenerated electron-hole showed a Z-scheme mechanism.145

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Colloid and Interface Science - Volume 487, 1 February 2017, Pages 410-417
نویسندگان
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