کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5134358 1492223 2016 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Using asymmetrical bipolar mode ion shutter to reduce induced voltage pulse in FT-IMS
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Using asymmetrical bipolar mode ion shutter to reduce induced voltage pulse in FT-IMS
چکیده انگلیسی


- Capacitance model is built and simulated to explain the mechanism of the produce of the induced voltage impulse.
- The induced voltage intensity can be effectively reduced by adjusting the voltage difference on the shutter grids.
- An adjustable asymmetrical bipolar ion shutter driver is developed to reduce the intensity of induced voltage.
- Experimental results show that the induced voltage surge decreases 77% comparing with the commonly used symmetrical mode.

Fourier transform ion mobility spectrometer (FT-IMS) works with high efficiency in ion utilization, whose two ion shutters switch simultaneously in a binary mode. When it works, an induced voltage surge is generated and detected by the electrometer during the voltage jump, which may badly decrease the quality of the ion signal detection. As the second ion shutter of FT-IMS is very close to the Faraday plate (less than 1 cm), the induced voltage surge gets so severe that it may even disguise the real ion signal. In this paper, the mechanism of production of the induced impulse is studied by simulation, and we developed an adjustable bipolar ion shutter driver to reduce the intensity of the induced impulse. The amplitude of square-wave voltage on each grid is adjustable, to decrease the errors caused by factors such as fix-errors of the BNG and the electromagnetic radiation difference of the two non-coplanar grids of TPG. In the experiment, the induced voltage surge decreases 77% comparing with the commonly used symmetrical drive mode. An FT-IMS spectra of 10 ppm of acetone is achieved with the new ion shutter driver.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: International Journal of Mass Spectrometry - Volume 409, 1 November 2016, Pages 38-43
نویسندگان
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