کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5139203 | 1494862 | 2017 | 19 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Sensitive determination of copper in water samples using dispersive liquid-liquid microextraction-slotted quartz tube-flame atomic absorption spectrometry
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Sensitive determination of copper in water samples using dispersive liquid-liquid microextraction-slotted quartz tube-flame atomic absorption spectrometry Sensitive determination of copper in water samples using dispersive liquid-liquid microextraction-slotted quartz tube-flame atomic absorption spectrometry](/preview/png/5139203.png)
چکیده انگلیسی
Determination of trace amount of copper in environmental samples is necessary due to its toxic properties and dangers to living organisms. Dispersive liquid-liquid microextraction (DLLME) was coupled with slotted quartz tube (SQT) to lower the detection limit for copper using flame atomic absorption spectrometry (FAAS). Parameters affecting the formation of copper-ligand complex, DLLME efficiency and SQT output were systematically optimized to improve copper detection signal. The SQT-FAAS, DLLME-FAAS and DLLME-SQT-FAAS systems were 2, 42 and 79 times, respectively, more sensitive than the conventional FAAS system. The limit of detection (LOD) and quantitation (LOQ) values obtained for the combined methods (DLLME-SQT-FAAS) were calculated as 0.7 and 2.2 μg Lâ 1, respectively. The method recorded appreciable recoveries for all samples tested (78%-99%), and experimental results of a certificated references material (EU-L-2) agreed with the certified value.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microchemical Journal - Volume 132, May 2017, Pages 406-410
Journal: Microchemical Journal - Volume 132, May 2017, Pages 406-410
نویسندگان
Gözde Ãzzeybek, Sezin Erarpat, Dotse Selali Chormey, Merve Fırat, ÃaÄdaÅ Büyükpınar, Fatma Turak, Sezgin Bakırdere,