کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5142247 1496033 2016 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
FTIR study of hydrogen bonding between substituted benzyl alcohols and acrylic esters
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
FTIR study of hydrogen bonding between substituted benzyl alcohols and acrylic esters
چکیده انگلیسی
Hydrogen bonding between substituted benzyl alcohols (benzyl alcohol, o-aminobenzyl alcohol, o-chlorobenzyl alcohol and o-nitrobenzyl alcohol) and acrylic esters (methyl methacrylate, ethyl methacrylate) is studied in carbon tetrachloride by using the FTIR spectroscopic method. Utilizing the Nash method, the formation constant (K) of the 1:1 complexes is calculated. Using the K value, the Gibbs free energy change (ΔG0) is also calculated. The calculated formation constant and Gibbs free energy change values vary with the substituent of benzyl alcohol and ester chain length, which suggests that the proton donating ability of substituted benzyl alcohols is in the order: o-aminobenzyl alcohol < benzyl alcohol < o-chlorobenzyl alcohol < o-nitrobenzyl alcohol, and proton accepting ability of acrylic esters is in the order: methyl methacrylate < ethyl methacrylate.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Arabian Journal of Chemistry - Volume 9, Supplement 2, November 2016, Pages S1410-S1415
نویسندگان
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