کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5142249 | 1496033 | 2016 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hexavalent chromium recovery by liquid-liquid extraction with 2-octylaminopyridine from acidic chloride media and its sequential separation from other heavy toxic metal ions
ترجمه فارسی عنوان
بازیافت کروم شش ظرفیتی با استخراج مایع با 2 اکتیلینینوپیریدین از مواد کلرید اسیدی و جداسازی پیوسته از دیگر فلزات سنگین سمی فلز
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی (عمومی)
چکیده انگلیسی
A systematic study of extraction of chromium(VI) with 2-octylaminopyridine (2-OAP) in xylene at room temperature has been conducted. Quantitative extraction of chromium(VI) was observed in the 0.4-0.8Â M concentration range of hydrochloric acid. From the extracted complex species in the organic phase, chromium(VI) was back extracted with 7Â N ammonia (3Â ÃÂ 10Â mL), and was determined by spectrophotometric method. Various parameters such as 2-OAP concentration, equilibrium period, effect of various diluents, aqueous: organic volume ratio, acidity and diverse ions were studied. The extraction reaction proceeds with ion-pair formation and the stoichiometry of extracted species was found to be [(2OAPH+) CrO3Clâ](org). The separation and determination of chromium(VI) from associated and toxic metals in binary, ternary and multicomponent mixture were carried out. The method permits the sequential separation of chromium(VI) from other toxic metals and has been used to separate and determine chromium(VI) from alloys, and effluent water samples from tannery industries.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Arabian Journal of Chemistry - Volume 9, Supplement 2, November 2016, Pages S1420-S1427
Journal: Arabian Journal of Chemistry - Volume 9, Supplement 2, November 2016, Pages S1420-S1427
نویسندگان
C.P. Mane, S.V. Mahamuni, S.S. Kolekar, S.H. Han, M.A. Anuse,