کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5142337 1496025 2017 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
New full-substituted cyclopropanes derived from the one-pot reaction of Meldrum's acid with aldehydes and BrCN in the presence of Et3N
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
New full-substituted cyclopropanes derived from the one-pot reaction of Meldrum's acid with aldehydes and BrCN in the presence of Et3N
چکیده انگلیسی
Reaction of 2,2-dimethyl-1,3-dioxane-4,6-dione (Meldrum's acid) with various aldehydes in the presence of cyanogen bromide and triethylamine leads to the selective and efficient formation of full-substituted cyclopropanes at room temperature. The products were obtained in good to excellent yields. Structure elucidation is carried out by 1H, 13C NMR, FT-IR spectroscopy and mass analysis techniques. A possible mechanism for the formation is discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Arabian Journal of Chemistry - Volume 10, Supplement 2, May 2017, Pages S1558-S1566
نویسندگان
, , , ,