کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5142418 | 1496025 | 2017 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermo-oxidation, friction-reducing and physicochemical properties of ricinoleic acid based-diester biolubricants
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Thermo-oxidation, friction-reducing and physicochemical properties of ricinoleic acid based-diester biolubricants Thermo-oxidation, friction-reducing and physicochemical properties of ricinoleic acid based-diester biolubricants](/preview/png/5142418.png)
چکیده انگلیسی
A major global effort is currently underway to reduce dependence on petroleum products and minimize the impact of their derivatives on the environment. Plant oils are being investigated as a potential source of environmentally favorable lubricants given their combination of biodegradability, renewability and excellent lubrication performance. Low oxidation and thermal stability, poor low-temperature properties and a narrow range of available viscosities, however, limit their potential application as industrial biolubricants. The chemical modification of plant fatty acid structures has great potential for improving the physicochemical and friction-reducing properties of these compounds. This paper presents the thermo-oxidation, friction-reducing and physicochemical properties of a series of diester compounds derived from ricinoleic acid as biolubricant basestocks. The results indicated that among the synthesized ricinoleic acid-based diester compounds, octyl 10,12-dihydroxy-9-behenoxystearate 16 has the lowest pour point (â53.26 °C), while octyl 10,12-dihydroxy-9-octyloxystearate 10 has the highest onset temperature (128.98 °C) and the lowest volatile loss and quantity of insoluble deposits (68.78% and 77.25%, respectively). The friction-reducing results indicate an improvement occurred in the presence of longer mid-chain esters and an increased polarity in the ester functional group. The data indicate that some synthesized derivatives have significant potential as environmentally friendly biolubricant basestocks.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Arabian Journal of Chemistry - Volume 10, Supplement 2, May 2017, Pages S2273-S2280
Journal: Arabian Journal of Chemistry - Volume 10, Supplement 2, May 2017, Pages S2273-S2280
نویسندگان
Nadia Salih, Jumat Salimon, Bashar Mudhaffar Abdullah, Emad Yousif,