کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5144939 | 1379189 | 2017 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Numerical simulations of sonochemical production and oriented aggregation of BaTiO3 nanocrystals
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی (عمومی)
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
Numerical simulations of sonochemical production and oriented attachment of BaTiO3 nanocrystals are performed in aqueous solution with pH 14. It is suggested that most significant effect of ultrasound is the dissolution of Ti-based gel in aqueous solution. It results in the dissolution-precipitation mechanism in the production of BaTiO3 nanoparticles, while with mechanical stirring without ultrasound it is the in situ mechanism that BaTiO3 is gradually formed on Ti-based gel. The oriented attachment of spherical BaTiO3 nanocrystals occurs by van der Waals torque (Casimir torque). Large aggregates of nanocrystals do not attach with each other as the repulsive double layer interaction is stronger for larger aggregates. For smaller spherical nanocrystals, the alignment of the crystal axes is less accurate due to more significant rotational Brownian motion of the nanocrystals.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ultrasonics Sonochemistry - Volume 35, Part B, March 2017, Pages 673-680
Journal: Ultrasonics Sonochemistry - Volume 35, Part B, March 2017, Pages 673-680
نویسندگان
Kyuichi Yasui, Kazumi Kato,