کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5151161 | 1498913 | 2017 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
One rare 3D unipolar pillared-layer framework with a 1D carboxyl-copper chain formed by the syn-anti-COO- group
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
One 3D pillared-layer coordination polymer has been prepared from a solvothermal reaction of Cu(NO3)2·3H2O with isophthalic acid (H2ipa) and 1,4-bis(imidazolyl)benzene (bib). The pyramid CuII node is connected by the ipa2 â ion and the bib spoke to afford a rare 3D unipolar pillared-layer framework. The overall topology can be described as a 6-connected self-catenated mab topology with point symbol of {44.610.8} through crosslink the (4,4) sheets. The weak AFM interaction in the 1D chain has been estimated as â 0.15 cmâ 1 by fitting the experimental data. Furthermore, the magneto-structural correlation has been well discussed.352
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 77, March 2017, Pages 14-17
Journal: Inorganic Chemistry Communications - Volume 77, March 2017, Pages 14-17
نویسندگان
Xue Zhang, Rui-Yu Zhu, Yi-Chen Liu, Qian Zou, Bang Chen, Jun-Jie Wang,