کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5151212 | 1498914 | 2017 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A inorganic-organic hybrid material constructed from the monolacunary polyoxomolybdates and multi-nuclear copper clusters
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A novel polyoxometalate (POM)-based inorganic-organic hybrid material constructed from the monolacunary Keggin-type polyoxomolybdates and the multi-nuclear copper clusters, namely, {[Cu8(tz)8(Htz)4(H2O)5][PMo10VIMoVO39]}â~10H2O (1) (Htz = 1H-tetrazole) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, IR spectra, PXRD analysis. In compound 1, bridged by the tz ligands, the six-nuclear copper clusters in the roof shape were obtained. These clusters are extended into the wave-like layers by the μ2-Htz ligands and the copper atoms in octahedron coordination geometry. The polyoxomolybdate anions act as the eight-connected node to link the layers into a 3D framework. In addition, the magnetic and photocatalytic properties of compound 1 have been investigated.370
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 76, February 2017, Pages 118-121
Journal: Inorganic Chemistry Communications - Volume 76, February 2017, Pages 118-121
نویسندگان
Xiao-Yuan Wu, Wen-Bin Yang, Wei-Ming Wu, Jian-Zhen Liao, Sa-Sa Wang, Can-Zhong Lu,