کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5427020 | 1508614 | 2017 | 19 صفحه PDF | دانلود رایگان |
- Global analysis of many rovibrational bands of CF4.
- This allows to simulate hot bands in the strongly absorbing 3μm region.
- The results allow to model 92% of the atmospheric absorption of this greenhouse gas.
- They have been used for spectroscopic database updates, including HITRAN2016.
CF4, or tetrafluoromethane, is a chemically inert and strongly absorbing greenhouse gas, mainly of anthropogenic origin. In order to monitor and reduce its atmospheric emissions and concentration, it is thus necessary to obtain an accurate model of its infrared absorption. Such models allow opacity calculations for radiative transfer atmospheric models. In the present work, we perform a global analysis (divided into two distinct fitting schemes) of 17 rovibrational bands of CF4. This gives a reliable model of many of its lower rovibrational levels and allows the calculation of the infrared absorption in the strongly absorbing ν3 region (1283â¯cmâ1 / 7.8â¯Î¼m), including the main hot band, namely ν3+ν2âν2 as well as ν3+ν1âν1; we could also extrapolate the ν3+ν4âν4 absorption. This represents almost 92% of the absorption at room temperature in this spectral region. A new accurate value of the C-F bond length is evaluated to re=1.314860(21)à . The present results have been used to update the HITRAN, GEISA and TFMeCaSDa (VAMDC) databases.
Journal: Journal of Quantitative Spectroscopy and Radiative Transfer - Volume 201, November 2017, Pages 75-93