Self-broadening coefficients and improved line intensities for the ν7 band of ethylene near 10.5μm, and impact on ethylene retrievals from Jungfraujoch solar spectra

- Extensive line intensities and self-broadening coefficients for the ν7 band of 12C2H4.
- Systematic discrepancies between the measured line intensities and HITRAN 2012.
- Empirical modeling of the self-broadening coefficients.
- Systematic reduction of the measured total columns of atmospheric C2H4 by −4.1±0.1%.

Relying on high-resolution Fourier transform infrared (FTIR) spectra, the present work involved extensive measurements of individual line intensities and self-broadening coefficients for the ν7 band of 12C2H4. The measured self-broadening coefficients exhibit a dependence on both J and Ka. Compared to the corresponding information available in the latest edition of the HITRAN spectroscopic database, the measured line intensities were found to be higher by about 10% for high J lines in the P branch and lower by about 5% for high J lines of the R branch, varying between these two limits roughly linearly with the line positions. The impact of the presently measured line intensities on retrievals of atmospheric ethylene in the 949.0-952.0 cm−1 microwindow was evaluated using a subset of ground-based high-resolution FTIR solar spectra recorded at the Jungfraujoch station. The use of HITRAN 2012 with line intensities modified to match the present measurements led to a systematic reduction of the measured total columns of ethylene by −4.1±0.1%.