کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5428633 1508685 2013 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Reference spectroscopic data for hydrogen halides, Part II: The line lists
ترجمه فارسی عنوان
داده های اسپکتروسکوپی مرجع برای هالید هیدروژن، قسمت دوم: لیست خط
موضوعات مرتبط
مهندسی و علوم پایه شیمی طیف سنجی
چکیده انگلیسی


- Significant improvements of line positions and intensities of hydrogen halides.
- Extended ro-vibrational range for non-LTE applications.
- First time inclusion of the deuterated species, DF, DCl, DBr and DI in HITRAN.
- Updated line-shape parameters.

Accurate spectroscopic parameters for the hydrogen halides, namely HF, HCl, HBr, and HI, together with their deuterated isotopologues, are crucial for the quantitative study of terrestrial and planetary atmospheres, astrophysical objects, and chemical lasers. A thorough evaluation of all the hydrogen halide line parameters in previous HITRAN editions has been carried out. A new set of line lists was generated for the HITRAN2012 edition using methods described here. In total, 131,798 entries were generated for numerous pure-rotational and ro-vibrational transitions (fundamental, overtone, and hot bands) for hydrogen halides and their deuterated species in a standard HITRAN 160-character format. Data for the deuterated isotopologues have been entered into HITRAN for the first time. The calculations employ the recently developed semi-empirical dipole moment functions [Li G, et al. J Quant Spectrosc Radiat Transfer 2013;121:78-90] and very accurate analytical potential energy functions and associated functions characterizing Born-Oppenheimer breakdown effects. Line-shape parameters have also been updated using the most recent available experimental and theoretical studies. Comparison with the previous HITRAN compilation has shown significant improvements.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Quantitative Spectroscopy and Radiative Transfer - Volume 130, November 2013, Pages 284-295
نویسندگان
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