کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5429163 | 1397337 | 2012 | 8 صفحه PDF | دانلود رایگان |
Analysis of the temperature dependence of the ratio of the intensity of two assigned and unassigned lines enables the determination of the most probable energy of the lower state of the unassigned transition. Such a new procedure has been applied to transitions of ammonia in the range 6626.0-6668.5 cmâ1 between 122 K and 300 K. This represents a first step in the considerable task of the assignment of the complete 1.5μm infrared spectral range.
⺠Ammonia spectra have been recorded from 300 K to 130 K at 1.5μm. ⺠Assignments in this range are partially known. ⺠Evolution of line relative intensities gives lower state of unassigned transitions. ⺠This information is quasi exhaustive in a given range. ⺠It represents a significant step towards global assignment.
Journal: Journal of Quantitative Spectroscopy and Radiative Transfer - Volume 113, Issue 11, July 2012, Pages 1084-1091