کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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5429542 | 1397358 | 2011 | 10 صفحه PDF | دانلود رایگان |
We use high quality ground-based solar absorption spectra measured in close coincidence with Vaisala RS92 radiosonde in situ water vapor profiles to demonstrate that a Voigt line shape model yields systematic errors in the remotely sensed tropospheric water vapor profiles. We analyse absorption signatures of 4 H216O and 2 HD16O bands situated between 790 and 4710Â cmâ1. We find that applying a speed-dependent Voigt line shape model instead of a Voigt line shape model significantly improves the agreement between the water vapor profiles obtained by the radiosondes and by infrared remote-sensing in the different bands. An optimal agreement is obtained for a Î2 (relaxation rate for speed-dependence) of 6-21% of Î0 (Voigt relaxation rate), which is consistent to the values derived from laboratory experiments. Our study suggests that further extensive laboratory investigations of line shape models are a key for improving the quality of modern water vapor remote sensing products.
Research Highlights⺠Line-shapes are very important for modern infrared remote sensing. ⺠Investigation of infrared water vapor line-shapes beyond the Voigt line-shape. ⺠Voigt versus speed-dependent Voigt line-shape model. ⺠Relaxation rate for speed-dependence parameters for different bands.
Journal: Journal of Quantitative Spectroscopy and Radiative Transfer - Volume 112, Issue 3, February 2011, Pages 465-474