کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5429693 | 1397366 | 2011 | 11 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis and enhanced photoluminescence in novel AucoreAu-Agshell nanoparticles embedded Nd3+-doped antimony oxide glass hybrid nanocomposites Synthesis and enhanced photoluminescence in novel AucoreAu-Agshell nanoparticles embedded Nd3+-doped antimony oxide glass hybrid nanocomposites](/preview/png/5429693.png)
AucoreAu-Agshell nanoparticles and Nd3+ ions co-doped in a novel antimony(III) oxide based dielectric (glass) matrix were synthesized for the first time, by a new very simple single-step methodology involving selective thermo-chemical reduction without employing any external reducing agent. They were characterized by the evolution of UV-vis-NIR absorption and photoluminescence spectra, XRD patterns, TEM and SAED images. XRD and SAED indicate the building of core-shell nanoparticles through the formation of (1Â 1Â 1) and (2Â 0Â 0) planes whereas TEM advocates the generation of spherical and spheroidal particles of 22-107Â nm sizes with various core morphologies. Photoluminescence upconversion exhibits two major emission bands of Nd3+ ions at 540 (green) and 649 (deep-red)Â nm which undergo about 5-fold intensity enhancement by the nanoparticles. Such enhancement is attributed to the local field effect induced by plasmonic Au-Ag nanoparticles to Nd3+ ions. These nanocomposites are promising for many nanophotonics applications.
âºSingle-step synthesis of AucoreAu-Agshell nanoparticles and Nd3+ ions co-doped novel antimony oxide glass. ⺠Both green and red upconversion emission of Nd3+ enhanced by â¼5 fold upon 805 nm excitation. ⺠Enhancement due to plasmon induced local field enhancement. ⺠Intelligent hybrid nanocomposites promising for several nanophotonics applications.
Journal: Journal of Quantitative Spectroscopy and Radiative Transfer - Volume 112, Issue 15, October 2011, Pages 2469-2479