کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5430421 1397402 2007 15 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Line intensity measurements in 14N216O and their treatment using the effective dipole moment approach.II. The 5400-11 000 cm-1 region
موضوعات مرتبط
مهندسی و علوم پایه شیمی طیف سنجی
پیش نمایش صفحه اول مقاله
Line intensity measurements in 14N216O and their treatment using the effective dipole moment approach.II. The 5400-11 000 cm-1 region
چکیده انگلیسی

The absorption spectrum of N2O, at room temperature, was recorded in the 5400-11 000 cm-1 region at resolutions ranging from 0.008 cm-1 near 5400 to 0.023 cm-1 near 11 000 cm-1 using a Bruker IFS120HR Fourier transform spectrometer. Sample pressure/absorption path length products ranging from 200 to 4700 mbar×m were used. More than 6000 absolute line intensities have been measured in 64 different bands of 14N216O. Using wavefunctions previously determined from a global fit of an effective Hamiltonian to more than 18 000 line positions [Tashkun SA, Perevalov VI, and Teffo JL, to be published], the experimental intensities measured in this work and by Toth [J Mol Spectrosc 1999;197:158-87] were fit using 62 parameters of a corresponding effective dipole moment, with residuals very close to the experimental uncertainty.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Quantitative Spectroscopy and Radiative Transfer - Volume 104, Issue 3, April 2007, Pages 342-356
نویسندگان
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