کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5430706 | 1397415 | 2008 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Temperature dependence of self- and N2-broadening coefficients of CH3Br ν6 band
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
طیف سنجی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Using absorption FT spectra (Bruker IFS 120, unapodized FWHM resolution â0.001 cmâ1), about 1400 lines, between 880 and 1050 cmâ1, and belonging to the ν6 band of both 12CH379Br and 12CH381Br isotopologues have been studied. Self- and N2-broadening coefficients are measured at various temperatures with an accuracy estimated to be around 10%. Their temperature-dependence exponents nself and nN2 have been derived with an accuracy estimated to be between 10% and 20%. A rotational dependence with the quantum number J has been observed for both nself and nN2, and has been empirically modeled using average values and polynomial expansions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Quantitative Spectroscopy and Radiative Transfer - Volume 109, Issue 4, March 2008, Pages 569-579
Journal: Journal of Quantitative Spectroscopy and Radiative Transfer - Volume 109, Issue 4, March 2008, Pages 569-579
نویسندگان
D. Jacquemart, H. Tran,