کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5431261 1508769 2017 14 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Binding energies: New values and impact on the efficiency of chemical desorption
ترجمه فارسی عنوان
انرژی های اتصال: ارزش های جدید و تأثیر در کارایی رسوب شیمیایی
موضوعات مرتبط
مهندسی و علوم پایه شیمی طیف سنجی
چکیده انگلیسی

Recent laboratory measurements have confirmed that chemical desorption (desorption of products due to exothermic surface reactions) can be an efficient process. The impact of including this process into gas-grain chemical models entirely depends on the formalism used and the associated parameters. Among these parameters, binding energies are probably the most uncertain ones for the moment. We propose a new model to compute binding energy of species to water ice surfaces. We have also compared the model results using either the new chemical desorption model proposed by Minissale et al. (2016) or the one of Garrod et al. (2007). The new binding energies have a strong impact on the formation of complex organic molecules. In addition, the new chemical desorption model from Minissale produces a much smaller desorption of these species and also of methanol. Combining the two effects, the abundances of CH3OH and COMs observed in cold cores cannot be reproduced by astrochemical models anymore.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Molecular Astrophysics - Volume 6, March 2017, Pages 22-35
نویسندگان
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