کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5477775 | 1399237 | 2016 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermal equation of state of a natural kyanite up to 8.55Â GPa and 1273Â K
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی هسته ای و مهندسی
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چکیده انگلیسی
The thermal equation of state of a natural kyanite has been investigated with a DIA-type, cubic-anvil apparatus (SAM85) combined with an energy-dispersive synchrotron X-ray radiation technique up to 8.55Â GPa and 1273Â K. No phase transition was observed in the studied pressure-temperature (P-T) range. The Le Bail full profile refinement technique was used to derive the unit-cell parameters. By fixing the bulk modulus K0 as 196Â GPa and its pressure derivative K0â² as 4, our P-V (volume)-T data were fitted to the high temperature Birch-Murnaghan equation of state. The obtained parameters for the kyanite are: V0Â =Â 294.05(9)Â Ã
3, α = 2.53(11) Ã 10â5 Kâ1 and (âK/âT)P = â0.021(8) GPaâKâ1. These parameters have been combined with other experimentally-measured thermodynamic data for the relevant phases to calculate the P-T locus of the reaction kyanite = stishovite + corundum. With this thermodynamically constrained phase boundary, previous high-pressure phase equilibrium experimental studies with the multi-anvil press have been evaluated.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Matter and Radiation at Extremes - Volume 1, Issue 5, September 2016, Pages 269-276
Journal: Matter and Radiation at Extremes - Volume 1, Issue 5, September 2016, Pages 269-276
نویسندگان
Qiang He, Xi Liu, Baosheng Li, Liwei Deng, Wei Liu, Liping Wang,