Experimental evidence of spin glass and exchange bias behavior in sputtered grown α-MnO2 nanorods

- We have synthesized the α-MnO2 nanorods by using DC reactive sputtering.
- We observed Spin glass and exchange bias behavior at low temperature in sputtered grown α-MnO2 nanorods.
- Exchange bias arises due to exchange coupling of uncompensated FM spins and AFM spins at FM/AFM interface.

Here, we present a single-step process to synthesize the α-MnO2 nanorods forest using reactive DC magnetron sputtering for the application of magnetic memories. The structural and morphological properties of the α-MnO2 nanorods were systematically studied using numerous analytical techniques, including X-ray diffraction, Raman spectroscopy, field-emission scanning electron microscopy and transmission electron microscopy. The magnetic measurements suggest that the α-MnO2 nanorods exhibit spin glass and exchange bias behaviour at low temperature. Such low temperature behaviour is explained by the core-shell type structure of nanorods. Antiferromagnetic core and shell of uncompensated ferromagnetic spins leads to the formation of antiferromagnetic/ferromagnetic (AFM/FM) interfaces, which originates exchange bias in the sample.

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