کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5490970 1524786 2017 19 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Magnetism on quasi-1-D lattices in novel non-centrosymmetric Ba3CrVS4O3 and in centrosymmetric La3TMWS3O6 (TM = Cr, Fe, Co)
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
Magnetism on quasi-1-D lattices in novel non-centrosymmetric Ba3CrVS4O3 and in centrosymmetric La3TMWS3O6 (TM = Cr, Fe, Co)
چکیده انگلیسی
La3TMWS3O6 (TM = Fe, Co) and novel Ba3CrVS4O3 can be obtained as pure polycrystalline samples by mineralizer aided solid-state reactions and a solid-state reaction with further purification by water, respectively. In contrast, La3CrWS3O6 needs a standard solid-state reaction to form but the final product contains observable impurities. All four compounds contain similar quasi-1-D magnetic lattices although La-based ones are centrosymmetric (P63/m) and the Ba-containing one is polar and non-centrosymmetric (P63). Strong antiferromagnetic couplings are observed along the magnetic chains in the Fe and Cr containing compounds. As a result, short-range magnetic order is suggested at low temperatures for the Fe-chain, which can be related to magneto-electric couplings. The Co3+-homologue shows typical diamagnetic behavior, as supported by its insulating nature, which is due to a low-spin state. The polar Cr3+-compound exhibits very different magnetic behavior compared to its corresponding non-polar relative. This proves a strong influence on the physical properties from the crystallographic symmetry.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetism and Magnetic Materials - Volume 435, 1 August 2017, Pages 126-135
نویسندگان
, , ,