Polypyrrole-encapsulated vanadium pentoxide nanowires on a conductive substrate for electrode in aqueous rechargeable lithium battery

• V2O5 nanowires on conductive substrate are obtained by annealing the NH4V4O10 nanowires.
• V2O5 nanowires are coated with polypyrrole (PPy) to form PPy@V2O5 nanocomposites.
• The PPy@V2O5 nanocomposites exhibit a high stable discharge capacity.
• A flexible PPy@V2O5//LiMn2O4 aqueous lithium battery is assembled and tested.

Precursors of ammonium vanadium bronze (NH4V4O10) nanowires assembled on a conductive substrate were prepared by a hydrothermal method. After calcination at 360 °C, the NH4V4O10 precursor transformed to vanadium pentoxide (V2O5) nanowires, which presented a high initial capacity of 135.0 mA h g−1 at a current density of 50 mA g−1 in 5 M LiNO3 aqueous solution; while the specific capacity faded quickly over 50 cycles. By coating the surface of V2O5 nanowires with water-insoluble polypyrrole (PPy), the formed nanocomposite electrode exhibited a specific discharge capacity of 89.9 mA h g−1 at 50 mA g−1 (after 100 cycles). A V2O5@PPy //LiMn2O4 rechargeable lithium battery exhibited an initial discharge capacity of 95.2 mA h g−1; and after 100 cycles, a specific discharge capacity of 81.5 mA h g−1 could retain at 100 mA g−1.

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