A real time in situ ATR-FTIR spectroscopic study of glyphosate desorption from goethite as induced by phosphate adsorption: Effect of surface coverage

The desorption of glyphosate from goethite as induced by the adsorption of phosphate was investigated by attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy in combination with adsorption isotherms. Desorption of glyphosate was very low in the absence of phosphate. Addition of phosphate promoted glyphosate desorption. At low initial surface coverages, added phosphate adsorbed on free surface sites, mainly, displacing a small amount of glyphosate. At high initial surface coverages, on the contrary, phosphate adsorption resulted in a significant glyphosate desorption. In the latter conditions, the ratio desorbed glyphosate to adsorbed phosphate was 0.60. The desorption process can be explained by assuming that phosphate adsorbs first forming a monodentate mononuclear complex, which rapidly evolves into a bidentate binuclear complex that displaces glyphosate.

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► Glyphosate desorption from goethite is promoted by the adsorption of phosphate.
► Phosphate adsorbs on free surface sites and sites previously occupied by glyphosate.
► Glyphosate desorption depends on the initial surface coverage with glyphosate.