کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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608762 | 880608 | 2011 | 9 صفحه PDF | دانلود رایگان |

New amphiphilic polyhedral oligomeric silsesquioxanes (POSSs) were synthesized, and their monolayer behavior on a water surface and Langmuir–Blodgett (LB) film formation were studied. Two kinds of amphiphilic POSS molecules, which have two or four di(ethylene glycol) units (2OH-DDSQ and 4OH-DDSQ, respectively), were synthesized by direct hydrosilylation of di(ethylene glycol) vinyl ether with double-decker shaped polyhedral oligomeric silsesquioxanes (DDSQs). Surface pressure (π)–area (A) isotherms and Brewster angle microscope (BAM) measurements indicated that both amphiphilic DDSQs form a stable monolayer at the air–water interface. In addition, 4OH-DDSQ can be deposited on a solid substrate by the LB technique. Atomic force microscope (AFM) images of a one-layer 4OH-DDSQ film showed a homogenous uniform surface on a hydrophilic silicon substrate, whereas nanometer scale dots were formed on a hydrophobic silicon substrate. Multilayer deposition on a hydrophobic substrate resulted in an increase of dot size with increasing deposition number of layers. Moreover, homogenous multilayer films with a few voids were obtained on a hydrophilic substrate. The results indicate that 4OH-DDSQ is a good candidate for preparing hybrid nanoassemblies.
Langmuir–Blodgett films of polyhedral oligomeric silsesquioxanes (POSSs) with well-defined structures were prepared using newly synthesized amphiphilic POSSs.Figure optionsDownload high-quality image (67 K)Download as PowerPoint slideResearch highlights
► Novel amphiphilic double-decker shape oligomeric silsesquioxane (DDSQs) were synthesized.
► The amphiphilic DDSQs formed stable monolayers at the air–water interface.
► Deposited monolayers showed different morphology depending on the surface nature of a substrate.
Journal: Journal of Colloid and Interface Science - Volume 355, Issue 1, 1 March 2011, Pages 106–114