AFM study of forces between silicon oil and hydrophobic–hydrophilic surfaces in aqueous solutions

An investigation has been made of the interactions between silicone oil and various solid substrates immersed in aqueous solutions. Measurements were made using an atomic force microscope (AFM) using the colloid-probe method. The silicone oil drop is simulated by coating a small silica sphere with the oil, and measuring the force as this coated sphere is brought close to contact with a flat solid surface. It is found that the silicone oil surface is negatively charged, which causes a double-layer repulsion between the oil drop and another negatively charged surface such as mica. With hydrophilic solids, this repulsion is strong enough to prevent attachment of the drop to the solid. However, with hydrophobic surfaces there is an additional attractive force which overcomes the double-layer repulsion, and the silicone oil drop attaches to the solid. There is circumstantial evidence that linear and nonlinear effect take part in force results from compression of the silicone oil film coated on the glass sphere.

Forces measured between a silica sphere coated by a film of silicone oil of viscosity 60,000 cS, and a flat mica substrate, 1 – in water, 2 – in 1.7 mmol/L NaCl, 3 – in 17 mmol/L NaCl. Theoretical curve was fitted into the samples.Figure optionsDownload high-quality image (50 K)Download as PowerPoint slide