Effects of surface mediation on the adsorption isotherm and heat of adsorption of argon on graphitized thermal carbon black

In this paper, the effects of surface mediation on the adsorption isotherm and isosteric heat of adsorption on a graphite surface were investigated, as the surface mediation is known to affect the intermolecular interaction of adsorbed molecules close to the surface. Kim and Steele (Phys. Rev. B 45 (11) (1992) 6226–6233) and others have assumed that the surface mediation is confined only to the first layer. This will be tested in this paper with a combined experimental and Grand Canonical Monte Carlo (GCMC) simulation of adsorption of argon on graphitized thermal carbon black (GTCB) over a range of temperatures (77–95.25 K). By matching the simulation results against the experimental data, we have found that the surface mediation is extended up to the fourth layer, rather than only the first as suggested by Kim and Steele, and the extent of this mediation is reduced with distance from the surface. This reinforces the important role of surface on the intermolecular interaction. With regard to the heat of adsorption, we found that the isosteric heats obtained directly from the simulation agree fairly well with the heats calculated from the application of the Clausius–Clapeyron equation on experimental isotherms of 77 and 87.3 K. The temperature dependence of the isosteric heat was investigated with the GCMC simulation results. One interesting observation is the existence of a heat spike at 77 K and its absence at higher temperatures, a phenomenon which is common to both simulation results and experimental data. This lends good support to the molecular model with surface mediation as a proper one to describe adsorption of noble gases on GTCB.

Comparison between the experimental isosteric heat and the GCMC simulation results without and with surface mediation.Figure optionsDownload high-quality image (91 K)Download as PowerPoint slide