Adsorption of Pd(II) complexes from chloride solutions obtained by leaching chlorinated spent automotive catalysts on ion exchange resin Diaion WA21J

It was found that Rh, Pd and Pt contained in the spent ceramic automotive catalysts could be effectively extracted by dry chlorination with chlorine. In order to concentrate Pd(II) contained in the chloride solution obtained from the dry chlorination process, thermodynamic and kinetics studies for adsorption of Pd(II) complexes from the chloride solutions on anionic exchange resin Diaion WA21J were carried out. It was found that Pd, Pt, Rh, Al, Fe, Si, Zn and Pb from the chloride solution could be adsorbed on the resin. The isothermal adsorption of Pd(II) was found to fit Freundlich, Langmuir and Dubinin–Kaganer–Radushkevich models under the adsorption conditions. The adsorption of Pd(II) on the resin was favorable according to the values of 1/n and RL from Freundlich and Langmuir adsorption isotherms, respectively. The maximum monolayer adsorption capacities Qmax based on Langmuir adsorption isotherms were 5.70, 4.84 and 4.05 mg/g and the corresponding value Xm based on Dubinin–Kaganer–Radushkevich were 5.55, 4.69 and 4.01 mg/g at temperatures 18 °C, 28 °C and 40 °C, respectively. The apparent adsorption energies (Ead) based on Dubinin–Kaganer–Radushkevich isotherm were −15.43, −16.22 and −23.57 kJ/mol for the temperatures 18 °C, 28 °C and 40 °C, respectively. Chemical adsorption was a main mechanism involved in the adsorption process. Pd(II) adsorption on the resin could be accelerated by increasing the adsorption temperature. The adsorption of Pd(II) from the chloride solution on the resin underwent pseudo-first order kinetic process and the apparent adsorption activation energy Ea was 15.0 kJ/mol. The intra-particle diffusion was a main rate controlling step in the Pd(II) adsorption process under the adsorption conditions.

Based on DKR isotherm, the apparent adsorption energies for Pd(II) were between −15.43 and −23.57 kJ/mol at 18–40 °C. Thus, chemical adsorption was main adsorption mechanism.Figure optionsDownload high-quality image (101 K)Download as PowerPoint slide