کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
610804 880659 2009 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of amidoalkyl group as spacer on aggregation properties of guanidine-type surfactants
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
Effect of amidoalkyl group as spacer on aggregation properties of guanidine-type surfactants
چکیده انگلیسی

Dodecanoyl amidoalkylguanidine hydrochlorides (C12AmG, m=2m=2, 3, 4, 6) are cationic surfactants that have an amidoalkyl group (Am) as spacer between the cationic guanidine and hydrophobic groups in the molecule. The effect of the Am group on the aggregation properties of the surfactants was evaluated through measurements of their critical micelle concentration (cmc) value, Krafft point, phase behavior, area occupied by one molecule at the air/water interface, and micellar aggregation number. Dodecylguanidine hydrochloride (C12A0G) with no Am group is a unique cationic surfactant because it exhibits a strong tendency for self-assembly when compared with common ionic surfactants, due to the hydrogen bonding between its guanidine groups in addition to the hydrophobic interaction between its alkyl chains [M. Miyake, K. Yamada, N. Oyama, Langmuir 24 (2008) 8527–8532]. In contrast, C12AmG showed a decreasing tendency for self-assembly with increasing alkyl chain length, m, of the Am group up to m=3m=3, above which the tendency increased. Such changes in aggregation tendency of the surfactants were suggested to arise from an increased bulkiness of the hydrophilic part caused by the Am group, resulting in a decrease in the hydrogen bonding between the guanidine groups and an increase in micellization through the cooperative hydrophobic interaction between the hydrophilic groups. From the balance of these effects, the area of the hydrophilic part of C12A4G was the largest and the hydrogen bonding between the guanidine groups in C12A4G was weakened. It is suggested in guanidine-type surfactant that A4 gave a similar aggregation tendency to traditional ionic surfactants and a weak effect for skin.

Effect of amidoalkyl group as the spacer in dodecylguanidine hydrochloride was studied.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Colloid and Interface Science - Volume 330, Issue 1, 1 February 2009, Pages 180–185
نویسندگان
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