کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
610976 | 880663 | 2009 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Cobalt-modified mesoporous MgO, ZrO2, and CeO2 oxides as catalysts for methanol decomposition
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
شیمی کلوئیدی و سطحی
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چکیده انگلیسی
Cobalt oxide-modified mesoporous CeO2, ZrO2, and MgO oxides and their SBA-15 silica analogues were prepared and characterized by XRD, TEM, N2 physisorption, FTIR, and TPR–TG analysis. Their catalytic activity in methanol decomposition to CO and hydrogen was tested. The support effect on the state and catalytic behavior of the loaded cobalt oxide nanoparticles is discussed. The best catalytic activity and selectivity of methanol decomposition to CO and hydrogen are registered for Co/CeO2.
Mesoporous oxides are suitable hosts for the preparation and stabilization of cobalt oxide nanoparticles. Their catalytic behavior could be successfully tuned, changing the nature of the support.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Colloid and Interface Science - Volume 333, Issue 1, 1 May 2009, Pages 277–284
Journal: Journal of Colloid and Interface Science - Volume 333, Issue 1, 1 May 2009, Pages 277–284
نویسندگان
Tanya Tsoncheva, Ljubomira Ivanova, Christo Minchev, Michael Fröba,