Influence of organic matter removal on competitive and noncompetitive adsorption of copper and zinc in acid soils

We studied competitive and noncompetitive adsorption of copper and zinc in four acid soils, and compared the behavior of the two metals in untreated samples and samples treated with hydrogen peroxide to remove organic matter in the soil. Copper exhibited stronger competitive adsorption than zinc in the untreated samples. However, removal of organic matter reduced copper adsorption to a greater extent than zinc adsorption, the two metals exhibiting a more similar adsorption pattern than the untreated samples. The presence of copper dramatically reduced zinc competitive adsorption in untreated samples; on the other hand, that of zinc only resulted in slightly reduced competitive adsorption of copper. The hydrogen peroxide treatment decreased competitive adsorption in both metals; however, copper continued to be more efficient than zinc in competing for binding sites on adsorbing surfaces. Desorption of Cu occurred much less readily than desorption of Zn and hysteresis is apparent especially for Cu.

(A) Example of noncompetitive adsorption in control samples (1530 μM); (B) noncompetitive adsorption in samples treated with H2O2; (C) competitive adsorption in control samples; (D) competitive adsorption in samples treated with H2O2.Figure optionsDownload as PowerPoint slide