Interaction of anionic dyes and cationic surfactants with ionic liquid character

The interactions of an imidazolium based ionic liquid (IL), namely 1-dodecyl-3-methylimidazolium chloride [C12mim][Cl] with two sulfonated anionic dyes, azocarmine G and methyl orange, are studied spectrophotometrically in both acidic and basic media. ILs (with some surface active character) can interact with the above dyes and cause considerable shifts in their spectra. These interactions are then compared with some surfactant–dye interactions. Evolving factor analysis (EFA) and multivariate curve resolution-alternating least squares (MCR-ALS) are used for complete resolution of the measured spectrophotometric data. The concentration and spectral profiles of all species were calculated without any assumption of the chemical models. The spectral variation of dye solutions as a function of IL concentrations below and above the critical aggregation concentration (CAC) is analyzed using MCR-ALS as a soft-modeling technique. The ion pair formation constants between ILs and dyes were calculated using the obtained concentration profiles.

Addition of an ionic liquid-like surfactant ([C12mim][Cl]) to methyl orange (pH 7) shows formation of dye–IL complexes at submicellar concentrations and dye–aggregate complexes at and above the critical aggregation concentration.Figure optionsDownload as PowerPoint slide