کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
612048 880690 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation and characterization of highly mesoporous spherical activated carbons from divinylbenzene-derived polymer by ZnCl2 activation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
Preparation and characterization of highly mesoporous spherical activated carbons from divinylbenzene-derived polymer by ZnCl2 activation
چکیده انگلیسی

Highly mesoporous spherical activated carbons (SACs) were prepared from divinylbenzene-derived polymers by ZnCl2 activation; the effects of activation temperature and retention time on the yield and textural properties of the resulting SACs were studied. SACs thus prepared were characterized by N2 adsorption, X-ray diffraction (XRD), scanning electron microscopy (SEM), and aqueous adsorption assays. All the SACs were generated with high yield (>54%) and high mesopore fraction (around 80%). SEM and XRD analyses of SAC28 verified the presence of the disordered micrographite stacking with developed mesoporosity. Compared with conventional activated carbons, SAC28 prepared in our study exhibited a comparable adsorption capacity of 190 mg g−1 for bisphenol A and even more excellent capacity of 330 mg g−1 for phenol. Bisphenol A preloading significantly reduced the adsorption capacity of SAC28 for phenol due to both reduction of adsorption sites and pore blockage.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Colloid and Interface Science - Volume 316, Issue 2, 15 December 2007, Pages 628–634
نویسندگان
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