کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
612051 880690 2007 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Density functional theory of adsorption in pillared slit-like pores
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
Density functional theory of adsorption in pillared slit-like pores
چکیده انگلیسی

We propose a density functional theory to describe adsorption of Lennard–Jones fluid in pillared slit like pores. Specifically, the pillars are built of chains that are bonded by their ends to the opposite pore walls. The approach we propose combines theory of quenched–annealed systems and theory of nonuniform fluids involving chain molecules. We compare the results of theoretical predictions with grand canonical ensemble Monte Carlo simulations and compute theoretical capillary condensation phase diagrams for several model systems.

Pore filled with an adsorbate (violet spheres). Blue spheres are the segments of pillars.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Colloid and Interface Science - Volume 316, Issue 2, 15 December 2007, Pages 652–659
نویسندگان
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