کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
612771 880706 2007 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Induced chirality of supramolecular assemblies of some amphiphiles with β-cyclodextrin through the interaction at the air/water interface
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
Induced chirality of supramolecular assemblies of some amphiphiles with β-cyclodextrin through the interaction at the air/water interface
چکیده انگلیسی

4-(N-Stearoylamino)-2-amino-azobenzene (AzoNH2C18) and 4-(N-stearoylamino)-azobenzene (AzoC18) have been synthesized. The inclusion complex formation of AzoNH2C18 and β-cyclodextrin (β-CyD) at the air/water interface was investigated and compared to that of AzoC18. It has been found that both the amphiphiles can form stable monolayer films on water surface. When the amphiphiles were spread on the aqueous solution of β-CyD, AzoNH2C18 can form inclusion complexes with the β-CyD molecules at the interface while AzoC18 cannot. The inclusion complex formation was confirmed by the changes in the isotherms and the circular dichroism (CD) and Fourier transform infrared (FT-IR) spectra of the transferred LS films. Atomic force microscopy (AFM) observation found morphological changes in the course of complex formation. It was suggested that the additional amino group in the azobenzene ring plays an important role in forming the inclusion complex in situ at the air/water interface.

The interfacial assemblies of two amphiphiles, 4-(N-stearoylamino)-2-amino-azobenzene (AzoNH2C18) and 4-(N-stearoylamino)-azobenzene (AzoC18), with β-cyclodextrin were investigated at the air/water interface. It has been found that while AzoNH2C18 formed inclusion complexes with β-CD in situ, AzoC18 could not.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Colloid and Interface Science - Volume 306, Issue 2, 15 February 2007, Pages 386–390
نویسندگان
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