Tribological behaviour of new chemically bonded PTFE polyamide compounds

Topic of the study is the formation of new PTFE polyamide materials by reactive extrusion. The new type of formed PTFE polyamide compound shows very good material properties. Recently it has been revealed that carboxylic acid groups exhibit a very high reactivity under polyamide melting conditions. PTFE micro powders functionalized by carboxylic acid groups are the base for the block copolymer formation in polyamide melts under defined process conditions. Such functionalized micro powders are formed from virgin PTFE by electron irradiation in the presence of oxygen. These new PTFE polyamide materials can be processed easily using commercial (common) process equipment like twin-screw extruders and injection molding. Many experimental investigations have been performed under dry sliding friction on PA 6, PA 6.6 and PA 12 compounds with PTFE weight portions between 3.3 and 50%. They show low coefficients of friction and low specific wear rates. The wear resistance of newly developed PTFE polyamide compounds is comparable with commercially available mechanically or physically produced PTFE and PEAK compounds.